By D. Michael P. Mingos
Chemical constitution and bonding. The scope of the sequence spans the total Periodic desk and addresses constitution and bonding matters linked to the entire parts. It additionally focuses realization on new and constructing components of contemporary structural and theoretical chemistry akin to nanostructures, molecular electronics, designed molecular solids, surfaces, steel clusters and supramolecular buildings. actual and spectroscopic thoughts used to figure out, learn and version constructions fall in the purview of constitution and Bonding to the level that the point of interest is at the clinical effects acquired and never on professional info in regards to the innovations themselves. concerns linked to the advance of bonding types and generalizations that light up the reactivity pathways and premiums of chemical strategies also are suitable. the person volumes within the sequence are thematic. The aim of every quantity is to offer the reader, no matter if at a school or in undefined, a finished assessment of a space the place new insights are rising which are of curiosity to a bigger clinical viewers. therefore every one evaluate in the quantity significantly surveys one point of that subject and areas it in the context of the amount as a complete. the main major advancements of the final five to ten years can be provided utilizing chosen examples to demonstrate the rules mentioned. an outline of the actual foundation of the experimental concepts which have been used to supply the first facts can also be acceptable, if it has no longer been coated intimately in other places. The insurance needn't be exhaustive in info, yet should still otherwise be conceptual, focusing on the recent ideas being built that would enable the reader, who's now not a consultant within the zone coated, to appreciate the information provided. dialogue of attainable destiny examine instructions within the zone is welcomed. evaluate articles for the person volumes are invited through the amount editors.
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Additional info for 50 Years of Structure and Bonding – The Anniversary Volume
Ishikawa R, Katoh K, Breedlove BK, Yamashita M (2012) Inorg Chem 51:9123 Single-Molecule Magnets and Related Phenomena 47 49. Vaz MGF, Allao Cassaro RA, Akpinar H, Schlueter JA, Lahti PM, Novak MA (2014) Chem Eur J 20:5460 50. Sessoli R (2008) Angew Chem Int Ed 47:5508 51. Ishii N, Okamura Y, Chiba S, Nogami T, Ishida T (2008) J Am Chem Soc 130:24 52. Coulon C, Cle´rac R, Wernsdorfer W, Colin T, Miyasaka H (2009) Phys Rev Lett 102:167204 53. Miyasaka H, Takayama K, Saitoh A, Furukawa S, Yamashita M, Cle´rac R (2010) Chem Eur J 16:3656 54.
1 Lanthanide Single-Molecule Magnets . . . . . . . . . . . . . . . . . . . . . . . . . 2 Organometallic and Low Coordination Number SMMs . . . . . . . . . . . . . . . 3 Single-Chain Magnets and Related Systems . . . . . . . . . . . . . . . . . . . . . 4 SMMs on Surfaces and on the Route to Spintronic Devices . . . . . . . . . . . . . R. P. uk 36 37 38 38 40 40 41 36 R. P. 5 Molecular Nanomagnets for Magnetic Cooling .
E. photomagnets. Three different kinds of photomagnets should be highlighted here: (1) photo-SMMs, (2) photo-SCMs and (3) photomagnets for which a 3D magnetic order is photoinduced. Interestingly, all these systems rely on two different photoactive mechanisms, the well-known spin-crossover properties of the FeII metal ion and the metal-metal electron transfer processes in cyanidobridged metal ion assemblies (Prussian blue analogues). In 2012, Oshio and co-workers reported the first photoinduced SMM in an hexanuclear Fe/Co Prussian blue analogue , and shortly after in 2013, Long, Smith and co-workers discovered the same photomagnetic properties in mononuclear Fe(II) spin-crossover complexes [78, 79].