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Extra resources for 4-TW/46-fs 10-Hz: Tisapphire laser system
Those aim to the favorable creation of enough reaction and separation driving forces and mutual synergy. In this class design variables such as as operation pressure, temperature, reﬂux ratio and phase velocity are of utmost importance. Moreover, chemical reaction regime and mass/heat transfer regime should be speciﬁed. The third and last class of design variables embraces all key spatial parameters, ranging from establishing section with diﬀerent functionalities, packing parameters, number of trays or length of sections, feeding and withdrawal points, energy exchange, section diameters, column ﬂowsheet conﬁguration with recycle structures and heat integration.
Quasi-homogenous, phase equilibrium models) are found to be well applicable, without compromising the output accuracy and reliability (Sundmacher and Hoﬀmann, 1999). The design requirements of commercial RD packings diﬀer to some extent from those in conventional distillation. For RD packing design two main features are to be taken into account (Subawalla and Fair, 1999): (i) the reaction eﬃciency should be maximized by providing intimate contact between vapor, liquid and solid catalyst, and (ii) the pressure drop through the catalyst bed should be minimized.
31) where fk is a nonlinear function of the distribution coeﬃcients. 1. 5. Schematic representation of the Film Model. The mass and heat transfer ﬂuxes are assumed to be positive in the direction liquid → vapor. 33) where kf,0 is the homogenously catalyzed forward rate constant evaluated at a reference temperature and Wcat is the amount of catalyst in the system. The deﬁnition of Damk¨ ohler number implies that no reaction takes place if Da << 1 and chemical equilibrium limit is reached if Da >> 1.